Natalie Maines Debuts New Song

People.com
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Dixie Chicks fans have waited nearly five years – since 2006’s Grammy-winning album Taking the Long Way – to hear new recorded material from Natalie Maines.

Now, she’s singing a new tune – and PEOPLE.com has your exclusive first listen.

Actually, the song isn’t so new: It’s a cover of the Beach Boys’s classic “God Only Knows” – recorded by Maines, 36, for the series finale of HBO’s Big Love, set to air March 20.

The song will also be available for sale on iTunes on March 15.