A crowd of migrants has broken down a barbed-wire fence on the Macedonia-Greece border using a steel pole as a battering ram.
TV footage showed migrants pushing against the fence at Idomeni, ripping away barbed wire, as Macedonian police let off tear gas to force them away.
A section of fence was smashed open with the battering ram. It is not clear whether any migrants got through.
Many of those trying to reach northern Europe are Syrian and Iraqi refugees.
About 6,500 people are stuck on the Greek side of the border, as Macedonia is letting very few in. Many have been camping in squalid conditions for a week or more, with little food or medical help.
The chaos on Monday erupted at a gate festooned with barbed wire, keeping migrants away from a railway line.
The protesters shouted “Open the border!” and threw stones at Macedonian police, who responded by firing rounds of tear gas to prevent them from getting through.
Macedonia and some other Balkan countries have erected fences in an attempt to reduce the influx of migrants, after more than a million reached Germany last year.
Greece is angry with Austria for having imposed a cap on migrant numbers. The crisis has left Greece shouldering much of the burden of housing migrants arriving in the EU from Turkey.
Many are refugees fleeing war in the Middle East, while others are escaping human rights abuses in Afghanistan, Eritrea and other conflict zones.
Merkel defends welcome
On Sunday German Chancellor Angela Merkel urged Europe to help Greece in the current migrant crisis.
In a TV interview she said: “Do you seriously believe that all the euro states that last year fought all the way to keep Greece in the eurozone, and we were the strictest, can one year later allow Greece to, in a way, plunge into chaos?”
She defended her decision last year to allow migrants in without a cap on numbers, saying she had no “Plan B”.
She has insisted that Germany can cope with the influx – and has a humanitarian duty to look after war refugees.
But her stance has been strongly criticised by some EU neighbours and some politicians in her ruling conservative CDU-CSU bloc.
Greece, under intense pressure from anxious EU partners, has erected extra reception centres on the Greek islands near Turkey, where thousands of migrants have been arriving daily.
Austria and Hungary have adopted a tougher stance than Germany. Hungary has fenced off its southern border and refuses to take in any non-EU migrants.